ABSOLUTE LINE STRENGTHS OF PHOSPHINE GAS IN THE 5 MICRON REGION

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1984

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Ohio State University

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Absolute strengths and wavenumbers of slightly over 200 vibration rotation lines of PH3 gas have been measured at 296K in the spectral regions near 2156, 2161, 2193 and 2208cm−1 using a tunable diode laser spectrometer. Line strength measurements were reproducible to better than 5% on average and the uncertainty in line positions wash less than 0.002cm−1. Selected PH3 lines have been pressure broadened with H2 gas and the results will be discussed.

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Author Institution: Chemistry Department, Lehigh University; Chemistry Department, Whitman College

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