ACETYLENE DISPERSED FLUORESCENCE SPECTRA ABOVE THE ISOMERIZATION BARRIER

Thumbnail Image

Files

1999-TA-05.jpg (58.43 KB)

Date

1999

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

Dispersed fluorescence spectra of the acetylene $bar{A} \rightarrow \bar{X}$ system have been recorded, and observed transitions in these spectra have been assigned which terminate on eigenstates with greater than $15,000 cm^{-1}$ of internal energy. Results for both ${^{13}}C_{2}H_{2}$ and ${^{12}}C_{2}H_{2}$ will be discussed, as well as implications for acetylene-vinylidene isomerization, which is expected to become feasible at $15,200 cm^{-1}.^{a}$

Description

$^{a}$ J.F. Stanton and J. Gauss, J. Chem. Phys. 110, 1831 (1999).
Author Institution: Department of Chemistry and George R. Harrison Spectroscopy Laboratory, MIT

Keywords

Citation

URI

http://hdl.handle.net/1811/19423

Collections

Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999