THE SLIGHTLY ASYMMETRIC ROTATOR. PERTURBATION THEORY BY CONTACT TRANSFORMATION

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1963

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Ohio State University

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“Perturbation calculations involving vibration-rotation interactions are usually simplified by subjecting the Hamiltonian to a contact transformation, $H’=THT^{-1}$, with $T = \exp(i\lambda S)$. The same technique may be useful in may be useful in many simpler problems. As a detailed example an S function is exhibited for the slightly asymmetric rotator, and analytical expressions are given for energy coefficients of the type tabulated by $Schwendeman.^{1}$”

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$^{1}$R. H. Schwendeman, J. Chem. Phys. 27, 986 (1957).
Author Institution: Randall Laboratory of Physics, University of Michigan

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http://hdl.handle.net/1811/8223

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969