SPECTROSCOPIC $B_{o}$ CONSTANTS OF RYDBERG $H_{3}$ AND $D_{3}$
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Date
1980
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Ohio State University
Abstract
A new technique was used for deriving spectroscopic constants by reference to the known constants of a related electronic state. Applications of this method to several diatomic molecules revealed its usefulness and encouraged its use with the triatomic hydrogen molecules. Spectroscopic $B_{o}$ constants for Rydberg states of $H_{3}$ and $D_{3}$ are obtained. Predicted and observed $B_{o}$ values for the upper state of the $3d(A_{1}{^{\prime\prime}}) \to A_{2}{^{\prime\prime}}(2p)$ band are 21.87and 21.96 $cm{-1}$ respectively.
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$^{1}$G. D. Carney, J. Chem. Physics (In press).
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