MCD SPECTRA OF Mn (III) PORPHYRINS IN THE FAR RED
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Date
1971
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Publisher
Ohio State University
Abstract
The far red MCD spectra of aquohalide and pyridine chelates of Mn (III) dimethyl proto and etio porphyrin have been measured and used to tentatively assign the spectrum. The lowest energy absorption band is identified as an $Eu^{*}$ $d\pi^{*}\leftarrow {d}\pi$ transition and two other bands are identified as charge transfer bands, thus generally confirming $Boucher’s^{1}$ interpretation of the spectra.
Description
$^{1}$L. J. Boucher. J. Am. Chem. Soc. 92, 2725 (1970) and J. Am. Chem. Soc. 90, 6640 (1968).""
Author Institution: Southwest Research Institute
Author Institution: Southwest Research Institute