ROTATIONAL PARAMETERS OF THE ETHANE TORSIONAL STATE FROM COMBINATION DIFFERENCES IN $\nu_{9}+\nu_{4}-\nu_{4}$

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1989

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Ohio State University

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Using interferometric spectra obtained on the McMath Solar Telescope FTS spectrometer in double pass configuration (0.0025cm−1 resolution), the ν9+ν4ν4 hotband has been assigned. The torsional splittings, on the order of 0.1cm−1, are clearly resolved. Lower state combination differences yield the following B4σ values: 0.6605099(77),0.6605005(44),0.6604930(54),0.6604846(77)cm−1 for σ−0,1,2,3 respectively. DJ4σ3 is determined to be 1.0261(68),1.0214(36),1.0158(49), and 1.0147(74)×10−6cm−1, respectively. DJK4σ yields 2.74(16),2.72(18),2.73(12), and 2.68(18)×10−1cm−1. Making use of the Fourier expansion formalism introduced by Lin and Swalen1 and further developed by Meerts and Ozier,2 Wong etal.3 and used by Moazzen-Ahmadi etal.,4 the results above have been analyzed further. We define effective constants by the following equations: Beff(v4σ)−Br,σBηb(1/2)<cos⁡(6γ)>+ξb<Pγ2>DeffJ(v4σ)−Dr,σJDJ+ηdj(1/2)<cos⁡(6γ)>+ξdj<Pγ2>DeffJK(v4σ)−Dr,σJDJK+ηdj(1/2)<cos⁡(6γ)>+ξdj<Pγ2>.In these equations, <..> are the diagonal values of the cos⁡(6γ) and Pγ2 matrices in the representation which diagonalizes the torsional Hamiltonian. The terms η× and ξ×,xb,dj,djk, are constant coefficients determined herein by fitting the appropriate equation to the results quoted above. Predictions of higher excited torsional state rotational parameters are presented.

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1 C. C. Lin and J. D. Swalen, Rev. Mod. Phys.31, 841-892 (1959). 2 W. L. Meerts and I. Ozier, J. Mol. Spectrosc. 94, 38-54 (1982). 3 M. Wong, I. Ozier, and W. L. Meerts, J. Mol. Spectrosc. 102,89-111 (1983). 4 N. Moazzen-Ahmadi, H. P. Gush, M. Halpren, H. Jagannath, A. Leung, and I. Ozier, private communication.


Author Institution: Molecular Spectroscopy Laboratory, Department of Physics and Astronomy, The University of Tennessee; Molecular Spectroscopy Laboratory, Department of Physics and Astronomy, Goddard Space Flight Center

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