RADIATIVE TRANSITION PROBABILITIES AND DIPOLE MOMENTS FOR ALL VIBRATIONAL LEVELS IN THE $X^{1}\Sigma^ +$ AND $A^{1}\Sigma^{+}$ STATES OF NaH

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1983

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Ohio State University

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Calculated radiative transition probabilities between all vibrational levels in the X1Σ+ state (v=0−21) and in the A1Σ+ state (v=0=29) of NaH are given. In addition, the calculated spontaneous emission lifetimes for vibrational-rotational levels (J=0,1) and the calculated dipole moments for these same levels are given. The calculation use new hybrid potential energy curves (based on Rydberg-Klein-Rees (RKR) and ab initio potential curves) and new ab initio dipole moment functions. The RKR curve for the X state is new1. The RKR curve for the A state2 and the at initio curves for both states3 are in the literature. The dipole moment functions of internuclear distance are also new1. 1 R. E. Olson, B, Liu, H. T. Zerke and W. C. Stwalley, to be submitted. 2 F. B. Orth, W. C. Stwalley, S. C. Yang and Y. K. Hsieh, J. Mol. Spectrosc. 79, 314 (1980). 3 R. E. Olson and B. Liu, J. chem. Phys. 73, 2817 (1980).""

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Author Institution: Department of Chemistry, Wartburg College Waverly; Iowa Laser Facility, University of Iowa

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