THE VARIABLE TEMPERATURE PRESSURE BROADENING AND PRESSURE SHIFT OF CO IN COLLISION WITH HELIUM

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1995

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Ohio State University

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Pressure broadening and pressure shift parameters have been measured for CO in collision with helium over a wide range of temperatures. This temperature range includes the high temperature semiclassical regime in which the physics of the collision is properly described by Anderson-like theories as well as the low temperature regime in which new phenomena associated with quasibound states require a more complete quantum mechanical description. Experimental results will be compared to theoretical predictions generated from a variety of CO-He potential energy surfaces. The discrepancy between experiment and the best available potential energy $surface^{1}$ will be discussed.

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1. R.J. LeRoy, C. Bissonette, T.H. Wu, A.K. Dham, and W.J. Meath, Farady Discuss., 97, 81 (1994)
Author Institution: The Ohio State University, 174 West 18th Avenue, Columbus, OH 43210-1106

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