MICROWAVE SPECTROSCOPY FROM $8.0-40.0$ GHz OF THE OH- ION IN THE KCI AND NaCl LATTICES AT $1.2^{\circ} K$.

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1969

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Ohio State University

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Microwave resonant absorption has been observed in OH−-doped KCl and NaCl crystals. Several lines were observed from 8−40 GHz by using relatively standard spectroscopic techniques. The zero-field spectra obtained here indicate that the OH− ion experiences a strong C4v potential in addition to the expected octahedral crystal field. The C4v potential probably arises from a shift of the OH− center of mass from the lattice site.

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Author Institution: Materials Research Laboratory and Noyes Chemical Laboratory, University of Illinois

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http://hdl.handle.net/1811/15866

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969