VIBRATIONAL ENERGY TRANSFER FROM CO AND $N_{2} O$ TO $^{15}N_{2}$ AND $^{14}N_{2}$ AND FROM HC1 TO $N_{2}$, $D_{2}$ AND CO AT LOW TEMPERATURE
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Date
1975
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
At low temperature an increasing of the vibrational energy transfer probability between molecules is observed. This effect is important when $\frac{{h}\Delta\nu}{{kT}}$ < 0.1 ($\Delta\nu$ is the difference of vibrational energy between the two colliding partners). The usual theories taking into account interactions involving long range forces cannot explain the observed trend. The discrepancies between theories and results will be analyzed.
Description
Author Institution: Laboratoire de Spectronomie Mol\'{e}culaire, C.N.R.S., Universit\'{e} Pierre et Marie Curie