COMBINATION BANDS IN THE O-H OVERTONE SPECTRA OF METHANOL: $THEORY^{*}$

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1983

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Ohio State University

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The $observed^\dag$ absorption spectra of methanol in the region of the O-H stretching overtones shows combination bands involving bands involving the O-H stretch and the H-O-C bend or the C-O stretch. A simple three coordinate model involving an anharmonic O-H stretch and harmonic H-O-C bend and C-O stretch coupled through C-matrix elements and potential constants accounts for the observed spectra. $^{*}$Supported in part by the standard Oil Company (Ohio) $^{1}$H.L. Fang, preceeding abstract.

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Author Institution: Department of Chemistry Syracuse, University Syracuse

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