INTENSITY ANOMALIES DUE TO A CORIOLIS RESONANCE IN THE SPECTRUM OF $H^{13}$ CNO
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Date
1989
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Ohio State University
Abstract
A collection of Coriolis-allowed bands have been observed in the far infrared spectrum of $H^{13}CNO$, recorded with the Bruker IFS 120 HR and a resolution of $0.003 cm^{-1}$. These bands are not detectable at all in the parent species. Each of these bands acquires intensity from the Coriolis resonance between the $(\nu_{4}, \nu_{5})^{1} = (02)^{0e}$ and $(10)^{1e}$ vibrational states. Further Coriolis-induced transitions have been found in the microwave region. The present work is concerned with deriving information from the intensity of the perturbation-allowed transitions.
Description
Author Institution: Physikalisch-Chemisches Institut, Justus Liebig Universit\""{a}t