HIGH RESOLUTION OBSERVATIONS OF LASER EXCITED FLUORESCENCE IN $NO_{2}$

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Date

1982

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Ohio State University

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Fluorescence of nitrogen dioxide excited by several lines of an argon ion laser has been dispersed and recorded with a resolution of $0.05 cm^{-1}$. The fluorescence wavelengths thus observed allow precise vibrational and rotational constants to be determined for high-lying vibrational states of $NO_{2}$. The ``continuum'' fluorescence reported by previous workers exhibits no identifiable structure even at high resolution.

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$^{1}$S. Butler, C.Kahler, and D.H. Levy, J. Chem. Phys. 62, 815 (1975).

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