LASER EXCITATION SPECTROSCOPY OF THE MONOMETHYLCYCLOPENTADIENYL COMPLEXES OF CALCIUM, ZINC AND CADMIUM
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Date
1991
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Publisher
Ohio State University
Abstract
Using a laser vaporization/photolysis technique, we have prepared metal monomethylcyclopentadienides $CaCH_{3}C_{5}H_{4}$, $ZnCH_{3}C_{3}H_{4}$, and $CdCH_{3}C_{5}H_{4}$, in a supersonic jet expansion and have recorded their electronic specta using laser-induced fluorescence spectroscopy. A vibrational analysis of the first few low-lying electronic states of these organometallic molecules will be presented. This study represents the first gas-phase synthesis and spectroscopic observation of these half-sandwich free radicals.""
Description
Author Institution: Laser Spectroscopy Facility, The Ohio State University