PRESSURE SHIFT MEASUREMENTS ON THE INFRARED LINES OF $^{12}CH+_{4}, ^{13}CH_{4}, ^{12}CH_{3}D$ AND $^{14}N_{2}O$ AROUND $7.85 \mu m$ USING A TUNABLE DIODE LASER$^{\dag}$
Loading...
Date
1988
Authors
Varanasi, P.
Chudamani, S.
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
Unless very careful and skillful precautions are taken, measurement of collision-induced line shifts using a tunable diode laser can be unreliable on account of the commonly encountered jitter and instability in the laser signal. However, when lines belonging to different molecules appear in the spectral scan as neighbors (reference lines) that do not interfere with the absorption of the observed line, as in the case of the three methanes and N2O, accurate line shift measurement is feasible. Using separate absorption cells for the reference and sample gases and placing them in series, we have been able to measure the pressure-induced shifts of the rotational lines of $^{12}CH_{4}, {^{13}}CH_{4}, {^{12}}CH_{3}D$ and $^{14}N_{2}O$ located between 1265 and $1275 cm^{-1}$. The temperature dependence of the shifts is also presented for collisions of the absorbers with $H_{2}, He, Ar, N_{2}, O$, and air.
Description
$^{\dag}$ Supported by the Planetary Atmospheres Branch of the Solar System Exploration Division of NASA under Grant-in-Aid No. NGR 33-015-139 and by the Upper Atmosphere Research Program of the Earth Sciences and Applications Division of NASA under Grant-in-Aid No. NAGW-1238.
Author Institution: Laboratory for Planetary Atmospheres Research, State University of New York
Author Institution: Laboratory for Planetary Atmospheres Research, State University of New York