FLUORESCENCE QUENCHING IN THE $B^{3}\Sigma_{0}+_{U}- b^{3}\Pi^{u}$ PERTURBED LEVELS OF $^{6}Li_{2}$

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1986

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Ohio State University

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Fluorescence in the $B^{3}\Pi_{o + u} - X^{1} \Sigma^{+}_{g}$ system of $I_{2}$ excited with a tunable single-frequency dye laser was recorded photoelectrically for pure iodine and iodine-foreign gas mixtures. From the measured relative intensities, energy transfer efficiencies for $\triangle v^{\prime}=\pm 1$ as well as the self and foreign gas quenching efficiencies have been determined for several vibrational and rotational levels of state B. From these studies, the v, J level of B at which one of the repulsive electronic states crosses is also estimated.

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$^{\ast}$ Research supported in part by NSERC Grant No. A-2440. Address: Department of Physics, Memorial University of Newfoundland, St. John's, Newfoundland, Canada. A1B 3X7
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