HIGH RESOLUTION INFRARED ANALYSIS OF THE $\nu_{6}(A''_{2})$ BAND OF CYCLOPROPANE-$D_{6}^{*}$

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1979

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Ohio State University

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The ν6(A2) parallel band of C3D6 near 2336cm−1 has been recorded with resolution between 0.018 - 0.024cm−1 on the University of Tennessee five meter Littrow spectrometer. The K-structure for each J value is unresolved below J = 20. Above this some structure is visible but cannot be assigned to specific K values. The Q branch is partially resolved into its J structure and two hot band Q branches are observed. Preliminary analysis of the ground state combination difference yielded B0=0.461410±0.000012cm−1 and D0J=(3.895±0.071)×10−7cm−1. Refined parameters for the ground and upper states will be reported.

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Research supported by the Planetary Atmospheres program of the National Aeronautics and Space Administration under Grant NGL-43-001-006.


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