THE ULTRAVIOLET ABSORPTIONS SPECTRUM OF MONOMETHYL DIAZIRINE

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Date

1971

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Ohio State University

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Abstract

Rotational fine structure has been recorded in the 0-0 band at 3424 \AA of the monomethyldiazirine spectrum. Comparison of the observed band contours with computed asymmetric top band synthesis reveals that the bands are type C polarized. The electronic assignment is therefore $^{1}A$^{\prime} -- $^{1}A$^{\prime\prime} (using the C, symmetry group), $\pi^{*}\leftarrow$ n transition. The rotational analysis will be discussed.

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Author Institution: Headquarters, US Army Missile Command, ATTN AMSMI-RRC, Restone Arsenal

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