THE MICROWAVE SPECTRUM OF METHYL $DIFLUOROSILANE^{*}$
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Date
1956
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Ohio State University
Abstract
The microwave spectrum of two isotopic species of methyl difluorosilane has been observed and assigned. From these spectra the structure, dipole moment and barrier to internal rotation have been determined. Several series of Q branch lines, assigned from $J = 6$ to $J = 12$, have been observed to be split into doublets. From these splittings the barrier has been calculated to be 1220 $\pm$ 50 cal.
Description
$^{*}$This research was made possible in part by support extended Harvard University by the Office of Naval Research under ONR Contract N5ori 76, Task Order V. $^{**}$Proctor \& Gumble Fellowship, 1955-56""
Author Institution: Department of Chemistry, Harvard University
Author Institution: Department of Chemistry, Harvard University