INTENSITY AND POLARIZATION OF EMISSION STUDIES ON $C_{6}H_{6}$ AND $C_{6}D_{6}$ IN 3-METHYLPENTANE GLASSES AT $77^{\circ} K$

Durnick, T. J.; Kalantar, A. H.

INTENSITY AND POLARIZATION OF EMISSION STUDIES ON $C_{6}H_{6}$ AND $C_{6}D_{6}$ IN 3-METHYLPENTANE GLASSES AT $77^{\circ} K$

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Date

1974

Authors

Durnick, T. J.

Kalantar, A. H.

Publisher

Ohio State University

Abstract

Polarization studies are hindered by emission intensity changes (caused by creation of a photo product) which can interfere with, e.g., relative emission quantum yield measurements. The polarization of the weak $b 2 g$ lines is found to be mostly, but not exclusively, in plane. If solvent perturbations and overlap are, as indicated, unimportant, this result Leads to unresolved inconsistencies with the $3 B 1 u$ assignment for the lowest triplet state of benzene.

Description

This work was supported by the National Research Council of Canada.

Author Institution: Department of Chemistry, University of Alberta Edmonton

URI

http://hdl.handle.net/1811/16388

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979

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