SUB-DOPPLER MEASUREMENTS ON THE ROTATIONAL TRANSITIONS OF CARBON MONOXIDE

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1997

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Ohio State University

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The frequencies of the first six rotational transitions of the CO molecule have been measured to an accuracy of $\pm 500 Hz$ in the frequency region up to 700 GHz. This high level of accuracy was achieved with the Cologne terahertz spectrometer operated in the sub-Doppler mode (1). To carry out precise CO Lamb-dip measurements, Least squares fits of the new CO, and 0.26 kHz, respectively. The experimental setup and the results of a fit to the Lamb-dip data combined with the frequencies up to 4.3 THz $(J = 38 \leftarrow 37)$ given by Evenson (3) will be presented. The analysis yielded a revised set of rotational constants for CO in its vibrational ground state, which is in good agreement with the previous values given by Varberg and Evenson(4).

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(1)G.Winnewisser, S.P.Belov, Th. Klaus, and \v{S} Urban, Z. Naturforsch. 51a, 200-206(1996). (2)S.P.Belov, F. Lewen, Th. Klaus, and G. Winnewisser, J.Mol. Spectrosc. 174, 606-612(1995). (3)K.M. Evenson, Private communication, 52 Okazaki Conference, Okazaki, Japan, March 1995. (4)T.D. Varberg and K.M. Evenson, {Astrophys. J.} 385,763-765(1992).
Author Institution: I. Physikalishes Institut, Universit\""at zu K\""oln

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