MOLECULAR BEAM OPTICAL STARK MEASUREMENTS OF ScS

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1997

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Ohio State University

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The molecular beam optical LIF spectrum of the $B^{2}\Sigma-X^{2}\Sigma^{+}$ band system of scandium monosulfide, ScS, has been recorded. The branch features associated with the low rotational levels were also recorded in the presence of a static electric held. The spectra were analyzed to produce magnetic hypefine parameters and permanent electric dipole moments. Comparisons with the theoretical predictions of Bauschlicher and $Langhoff^{g}$, and experimentally determined values for $SeO^{4}$ are made.

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$^{g}$C. W. Bauschlicher, Jr and S. R Langhoff, J Chem Phys. 85. 5936 (1986) $^{h}$J. Shirley, C. Scurlock, and T. C. Steimle. J. Chem Phys. 93 1568 (1990)
Author Institution: Dept. of Chemistry and Biochemistry, Arizona State University

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http://hdl.handle.net/1811/13865

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999