HIGH RESOLUTION, ROTATIONALLY RESOLVED ELECTRONIC SPECTRA OF $MgCH_{3}$.

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1995

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Ohio State University

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Very little spectroscopic information is available about Mg-containing species even though they have considerable astrophysical importance and play a significant role in biological systems. The present work reports the first high resolution spectroscopic study of the MgCH3 radical. Rotationally resolved spectra have been recorded and analyzed for both spin-orbit components of the 000 band of the A~2EX~2A1 transition in MgCH3. The free radicals were obtained using the laser ablation/photolysis techniquea and their laser-induced-fluorescence probed in a supersonic free-jet expansion. Analysis of the spectra yields the molecular constants in the X~ and A~ states. No Jahn-Teller effect was detected for this radical. A discussion of the fitted constants and the geometry proposed for MgCH3 will be presented.

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aTimothy M. Cerny, James M. Williamson and Terry A. Miller J. Chem. Phys. 102, 2372 (1995).


Author Institution: The Ohio State University, Columbus, OH 43210

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