HIGH RESOLUTION STUDY OF A CAGE MOLECULE, DABCO, BY LASER INDUCED FLUORESCENCE

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1992

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Ohio State University

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Both 1- and 2-photon rotationally resolved spectra of the $S_{1}\leftarrow S_{0}$ transition in jet cooled trietilene- diammine (DABCO) were observed in the spectral region around 280nm. In addition to $e^{\prime}$ modes, accessible by 1-photon ""perpendicular"" transition, and $a^{\prime}_{1}$ modes, by 2-photon ""parallel"" transition, we will present results on $a^{\prime\prime}_{2}$ modes, accessible by 1-photon ""parallel"" transition, and $a^{\prime}_{1}$ modes, accessible by 1-photon ""quadrupole"" transition.

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Author Institution: Molecular and Laser Physics, University of Nijmegen

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