ENHANCEMENT OF INFRARED ABSORPTION BANDS OF CHARGE TRANSFER $COMPLEXES^{*}$

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1958-H-09.jpg (75.25 KB)

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1958

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Ohio State University

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“An enhancement of infrared absorption bands due to change in vertical ionization energy or change in vertical electron affinity during the course of molecular vibration is shown to be inherent in charge-transfer theory. A semiquantitative calculation of the intensity enhancement of the symmetric ring stretching vibrational mode of benzene in the benzene-iodine complex agrees well with the experimentally observed value. Consequently, earlier objections to a symmetrical model for the complex may not be valid.”

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$^{*}$This research was supported by the United States Air Force through the Air Force Office of Scientific Research of the Air Research and Development Command under contract No. AF 49(638)-35.
Author Institution: Departments of Physics and Chemistry, The University of Texas

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http://hdl.handle.net/1811/7748

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1946-1959