Spectroscopy and Predissociation Dynamics of Hydrogen Bonded Complexes

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1993

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Ohio State University

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The high resolution spectra of the linear HCN-HCCCCH, HCCCN-HCCH complexes have been studied using the optothermal technique. The structures of these complexes have been characterized. The predissociation lifetimes of the ν=1 state of the hydrogen bonded C-H stretches have also been determined. The properties of these complexes, along with the previous studied HCN-HCCH, are compared in detail. The differences of the intermolecular forces among these systems are also discussed.

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Author Institution: Department of Chemistry, Princeton University

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http://hdl.handle.net/1811/18718

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1990-1999