LONG RANGE FORCES IN THE HALOGENS.

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1969

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Ohio State University

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The second order dispersion term in the perturbation development of the long range interaction of two non-overlapping halogen $^{2}P$ atoms is diagonal in $\Omega, +, -, g$, and u character. The form of the potential inclusive of first order quadrupole and the second order effects will be discussed for the $0_{u}^{+}$ and lowest $0_{g}^{+}$ states in the halogens as well as perturbations near dissociation in the $^{3}\Pi_{1}$ state of ICI.

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Author Institution: Department of Chemistry, Atlanta University

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