THE STRUCTURE OF ETHYLENE OZONIDE

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1975

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Ohio State University

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Few polyatomic molecules have had as many isotopic species assigned as ethylene ozonide--fourteen isotopic species. This surfeit of data permits various routes to the structure. Some of the more interesting $r_{s}$ bond lengths ({\AA}) and angles are $O_{p}O_{p} = 1.470, O_{p}C = 1.395, O_{e}C = 1.425, < COC = 103.9^{\circ}, < O_{e}CO_{p} = 105. 9^{\circ}$ and $< COpOp= 99,3^{\circ}$. The ro bond lengths differ from the $r_{s}$ values by 0,002 to 0,02 {\AA} depending on the bond and the method of calculation.

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Author Institution: Department of Chemistry, University of Michigan; Department of Chemistry, Harvard University

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