VIBRATIONAL CIRCULAR DICHROISM IN THE CH STRETCHING REGION OF A SERIES OF SIMPLE SUGARS

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1979

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Ohio State University

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We have investigated the VCD spectra of about 20 simple sugars and find rich variations in both magnitude and sign of the circular dichroism associated with each of the CH stretching modes from one sugar to the next. We discuss the vibrational assignment of these CH stretching modes and the correlation of the observed circular dichroism with the asymmetric configurations of the individual carbon atoms.

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