A STUDY OF ACCIDENTAL CORIOLIS RESONANCE IN HYDROGEN SULFIDE

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1966

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Ohio State University

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A specific Hamiltonian for the nonlinear XYX molecule has been obtained by applying the results of Chung and $Parker^{1}$ to the general second order expansion of H given by H. H. $Nielsen^{2}$. Vibrational matrix elements have been calculated and a procedure for vibrational diagonalization which takes into account accidental Coriolis resonance will be outlined. Specific applications to $H_{2}S$ will be indicated. Supported by the Air Force Cambridge Research Laboratories, Office of Aerospace Research, U. S. Air Force, Contract No. 19-628-4009.

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$^{1}$ K. T. Chung and P. M. Parker, J. Chem. Phys. 43, 3869 (1965). $^{2}$ H. H. Nielsen, Rev. Mod. Phys. 25, 90 (1951).
Author Institution: Department of Physics and Astronomy, Michigan State University

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http://hdl.handle.net/1811/14976

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1960-1969