THE MICROWAVE SPECTRUM AND STRUCTURE OF TRIMETHYLAMINE-TRIMETHYLBORON
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Date
1977
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Ohio State University
Abstract
The microwave spectrum of samples of $Me_{3}N-BMe_{3}, Me_{3}^{15}N-BMe_{3}$, and $(CD_{3})_{3}-BMe_{3}$ have been investigated. These weak adducts give rise to broad absorption bands with some resolvable structure. Efforts at assigning the spectral details and determining the ground state $B_{O}$’s have not been completely successful. Nevertheless, using the isotope shifts a value of 1.70 $\pm 0.02 {\AA}$ for d(B-N) can be obtained and estimates can be made for the other structural parameters.
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Author Institution: Department of Chemistry, The University of Michigan