HEAVY ATOM EFFECTS ON THE PHOSPHORESCENCE DECAY RATES OF SOME CYCLIC KETONES

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1977

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Ohio State University

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The effects of a heavy atom on the phosphorescence rate constants of some cyclic ketones were studied in several host single crystals. Included in this study were cyclohexanone and cyclohexanedione in crystals of p-dichlorobenzene and p-dibromobenzene. The trends in the phosphorescence rate constants and zero field splittings of the triplet state as a function of halogenated hosts will be discussed.

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Author Institution: Department of Chemistry, Wichita State University

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