MICROWAVE SPECTRUM OF METHYL $MONOFLUOROSILANE^{*}$

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1956

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Ohio State University

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The rotational constants of two isotopic species of methyl monofluorosilane, as determined from microwave data, have been used to calculate its structure. Quantitative Stark effect data has been obtained and used to calculate the dipole moment. Certain absorption lines in the microwave spectrum were found to be split into doublets. These splittings are due to internal rotation and have been used to determine the barrier to internal rotation. This barrier was found to be. 1450 cal. + 50 cal.

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∗This research was made possible in part by support extended Harvard University by the Office of Naval Research under ONR Contract N5ori 76, Task Order V.""


Author Institution: Department of Chemistry, Harvard University

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http://hdl.handle.net/1811/7515

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1946-1959