MICROWAVE SPECTROSCOPY AND PROTON TRANSFER DYNAMICS IN THE FORMIC ACID-ACETIC ACID DIMER
Date
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
The rotational spectrum of the doubly hydrogen-bonded \textit{hetero} dimer formed between formic acid and acetic acid has been recorded between 4 and 18 GHz using a pulsed-nozzle Fourier transform microwave spectrometer. Each rigid-molecule rotational transition is split into four as a result of two concurrent tunnelling motions, one being proton transfer between the two acid molecules, and the other the torsion/rotation of the methyl group within the acetic acid. We present a full assignment of the spectrum for \textit{J} = 1 to \textit{J} = 7 for these four torsion/tunnelling states. Spectra have been observed for the main isotopic species , \textbf{134}, 054316 (2011).}, with deuterium substitution at the C of the formic acid and all
Description
Author Institution: Department of Chemistry, Oxford University, South Parks Road, Oxford, OX1 3QZ, United Kingdom; Department of Chemistry, Amherst College, Amherst, MA 01002; Department of Chemistry, University of Rochester, Rochester, NY 14627