HIGH RESOLUTION FITR SPECTROSCOPY IN $C_{2}H_{4}$ USING A SLIT-JET: OVERTONE IN THE $5000cm^{-1}$ REGION

Loading...
Thumbnail Image

Date

1998

Journal Title

Journal ISSN

Volume Title

Publisher

Ohio State University

Research Projects

Organizational Units

Journal Issue

Abstract

A fourier transform interferometer was used to record the slit jet cooled overtone absorption spectruma of 12C2H4 between 3900 and 7900cm−1 at a spectral resolution of 0.02cm1 and a rotational temperature of 53K. In this high frequency range. We perform the analysis of 17 combination bands. For some of them located at 4206, 4322, 4328, 4515, 4730, 5995, and 6150cm−1 the analysis was complicated by the existence of A-type B-type and C-type Coriolis-type resonances with dark states. For each analysed spectral region, a preliminary calculation of the energy levels was performed taking into account the observed resonances.

Description

a R. Georges, M. Bach, and M. Herman. Mol. Phys. 90. 381 (1997).


Author Institution: Laboratoire de Chimie Physique Mol'{e}culaire CP 160/09, Universit'{e} Libre de Bruxelles; Laboratoire de Photo-physiqu Mol'{e}culaire, CNRS Universit'{e} Paris Sud, Campus d'Orsay

Keywords

Citation