1-PHENYLPYRROLE A TICT MOLECULE?.
Loading...
Date
2009
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
1-Phenylpyrrole has been identified by several authors as a molecule that displays twisted intramolecular charge-transfer (TICT) character in the condensed phase. However, Suzuka and coworkers , \textbf{109}, 7185 (1998) and references therein.}, using single vibronic level dispersed fluorescence, observed no evidence of TICT activity in the gas phase. In this work, 1-phenylpyrrole is studied by the high resolution methods previously applied to DMABN , \textbf{ 122}, 084309 (2005).} to determine the extent of its motion along different possible TICT coordinates when it absorbs light.
Description
K. Okuyama, Y. Numata, S. Odawara, and I. Suzuka, \textit{J. Chem. Phys.A. E. Nikolaev, G. Myszkiewwicz, G. Berden, L. Meerts, J. F. Pfanstiel, and D. W. Pratt, \textit{J. Chem. Phys.Work supported by NSF CHE-0615755
Author Institution: Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260; Division de Ciencias e Ingenierias, Campus Leon, Universidad de Guanajuato, Leon, Gto. 37150, Mexico
Author Institution: Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260; Division de Ciencias e Ingenierias, Campus Leon, Universidad de Guanajuato, Leon, Gto. 37150, Mexico