THE $\nu_{6}$ BAND OF $C_{3}O_{2}$

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1984

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Ohio State University

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Spectra of C3O2 near 540cm−1 have been recorded with a Bomem interferometer at an apodized resolution of 0.004cm−1. After deconvolution an effective line width of ∼0.0018cm−1 has been attained enabling significant progress to be made in the analysis. In addition to confirming an earlier analysis(1) of the fundamental, many of the levels involving up to 3 quanta of the low lying bending vibration ν7, have also been identified and analysed. Aspects of the vibrational Renner-Teller effect will be discussed.

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(1) L. Halonen, I. M. Mills and J. Kauppinen, Mol. Phys. 43, 913 (1981).


Author Institution: Physikalische-Chemisches Institut, Justus Liebig Universit""{a}t; Herzberg Institute of Astrophysics, National Research Council of Canada

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