INFRARED SPECTRA AND ANHARMONIC FORCE FIELD OF $N_{3}^{-}$ ISOLATED IN KCl, KBr, AND KI

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1975

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Ohio State University

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Abstract

$N_{3}^{-}$ and $^{15}$$NNN^{-}$ have been isolated in KCl, KBr, and KI using the alkali halide pressed disk technique. The infrared spectra of the pellets have been obtained at several temperatures and a number of not bands have been identified. The anharmonic force field of $N_{3}^{-}$ has been determined using a simplified quartic force field.

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Author Institution: Science Research Laboratory, U.S. Military Academy

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