SPECTROSCOPY OF THE I$2$ MOLECULE IN CRYOGENIC MATRICES OF FLUORINE CONTAINING MOLECULES.

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2009

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Ohio State University

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\maketitle The spectroscopy of the I$_2$ molecule in CF$_4$, C$_2$F$_6$, C$_3$F$_8$ and C$_4$F$_{10}$ cryogenic solids was studied for the first time with use of steady-state one photon excitation in the Vac UV region and two photon laser excitation. In this contribution we discuss spectra and temporal behaviour of emission originating from the ion-pair states of I$_2$. Preliminary results for some other molecular matrices will be presented as well.

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Author Institution: Insititute of Physics, St.Petersburg State University, 198504 St.Petersburg, Russia; Department of Chemistry, National University of Ireland, Maynooth, Ireland

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