DIODE LASER SPECTRUM OF JET-COOLED $CH_{2}F_{2}$ IN THE 9-10 $\mu m$ REGION
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Date
1997
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Ohio State University
Abstract
Utilizing $CO_{2}$ laser optical pumping in the 9-10 $\mu m$ region, methylene fluoride is a common gain medium in far-infrared gas lasers. Unfortunately this part of methylene fluoride’s infrared spectrum is very dense and not well characterized, making it difficult to identify the transitions responsible for FIR laser action. Four vibrational bands ($\nu_{3}, \nu_{7}, \nu_{9}, \nu_{4}$) are present with several Coriolis coupled to one another. Hot bands and high-{J} transitions contribute to the congestion. Rotational and vibrational cooling of methylene fluoride in a pulsed-jet expansion leads to a much simpler spectrum which we have obtained using a tunable diode laser spectrometer, Win-k on the $\nu_{3} \nu_{7}$ and $\nu_{9}$ bands has been completed and Coriolis effects have been studied.
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Author Institution: Department of Chemistry, Amherst College