INFRARED AND RAMAN SPECTRA OF CRYSTALLINE $SO_{2}F_{2}$
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Date
1973
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Ohio State University
Abstract
Infrared and Raman spectra of crystalline sulfuryl fluoride suggest that the molecules in both solid phases of this compound occupy sites of $C_{s}$ or $C_{1}$ symmetry in a non-cubic primitive cell. Our results point to well-ordered structures, even though previous specific heat measurements and spectroscopic data have suggested partial disorder in this solid, as evidenced by a small residual entropy at $0^{\circ} K$ (0.58 e.u.).
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Author Institution: Department of Chemistry, Laval University