THE RAMAN SCATTERING INTENSITY PARAMETERS OF ACETYLENE
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Abstract
The Raman trace scattering cross sections for CH strectching vibration may be described in terms of derivatives of the mean molecular polarizability with respect to the CH stretching internal coordinate. There is in general good aggreement between values for these parameters obtained from experimental absolute intensity studies and those calculated by ab initio qunatum mechanical techniques. In particular, this has been verified for the cases of methane, ethane, n-propane, cyclohexane and ethylene. One apparent exception to this result is acetylene, for which this derivate is calculated to be significantly smaller than the experimental value, when compared with the results for other
Description
Author Institution: Department of chemistry and Biochemistry, University of Guelph; Division of Chemistry, National Research Council of Canada