A NEW LOOK AT AN OLD MOLECULE: THE VIBRONIC SPECTROSCOPY OF $\rho-DIFLUOROBENZENE (-d_{4})$

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Date

1991

Authors

Elston, Harry J.
Todd, Fred G.
Parmenter, C. S.

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Ohio State University

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Abstract

As a prelude to future studies of molecular dynamics, the vibronic supersonic jet spectroscopy of the S1(1B2uSo(1Ag) transition of p-difluorobenzene-d4 (pDFB-d4) has been investigated for the lower 1600 cm−1 of the S1 vibrational manifold. Dispersed single vibronic level fluorescence spectroscopy has been used to establish 12 S1 fundamental frequencies. Significant spectroscopic differences from light pDFB occur. Two forhidden transitions not seen in the light molecule are observed, one being a second order Herzberg-Teller transition. Additionally, transitions with activity in a totally symmetric mode (ν4) that is inactive in light pDFB dominate the vibronic spectra of pDFB-d4. We explore with Franck-Condon analysis the reasons why this fundamental is not seen in the light molecule.""

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Author Institution: Department of Chemistry, Indiana University; Department of Chemistry, Colorado State University

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