INTERACTION BETWEEN DIFFERENT COHERENT RAMAN VIBRATIONS DURING STIMULATED RAMAN PROCESS IN SINGLE COMPONENT LIQUIDS.

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1965

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Ohio State University

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Stimulated Raman effect is observed in benzonitrile, ** liquid. This molecule possesses two equally intense and narrownormal Raman lines, one due to the C-C ($1000 cm^{-1}$) and the other to the $C\equiv N (2250 cm^{-1}$) stretching modes. The stimulated Raman spectrum shows a number of stokes and antistokes lines corresponding to these two modes, as well as lines at frequencies which are the sum and difference of the frequencies of these two vibrations. A mechanism will be discussed which accounts for the intensity and frequency of the observed combination lines. The application of this method in producing new intense coherent frequencies will be indicated.

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Author Institution: Electro Optical Systems, Inc.; Department of Chemistry, University of California; Electro Optical Systems, Inc., University of California

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