FITTING OF ASYMMETRIC TOP ROTATIONAL ENERGIES

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1974

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Ohio State University

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Abstract

Theindeterminacy of the centrifugal distortion coefficients of an asymmetric top can be eliminated in a variety of ways.1 A computer program has been written Co examine the fitting of rotational energy levels with various forms of the reduced Hamiltonian. The application of this program to the spectra of several molecules will be described.

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1J.K.G. Watson, J. Chem. Phys. 46, 1935 (1967).


Author Institution: Department of Physics, The Ohio State University

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