INVESTIGATION OF THE 550 nm REGION OF SUPERSONICALLY COOLED $NO_{2}$

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1983

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Ohio State University

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The visible system of nitrogen dioxide is notoriously $complex.^{1}$ Low resolution absorption spectra clearly shows a sudden increase in intensity and in complexity beginning at about 550 nm. We report our investigation of the 550 nm region of $NO_{2}$ cooled in a supersonic expansion, and we discuss the relationship of this change to the electronic states of the molecule. $^{1}$D.K. Hsu, D.L. Monts, and R.N. Zare, Spectral Atlas of\_{N}itrogen Dioxide (Academic press New York, 1978).

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Author Institution: Department of Chemistry, University of Arkansas Fayetteville

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