TORSIONAL POTENTIAL FUNCTION OF ETHYLPHOSPHINE

Groner, P.; Durig, J. R.

TORSIONAL POTENTIAL FUNCTION OF ETHYLPHOSPHINE

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Date

1985

Authors

Groner, P.

Durig, J. R.

Publisher

Ohio State University

Abstract

Microwave spectra of new isotopic species of ethylphosphine $C H 3 C H 2 P H 2$ were assigned to derive an improved molecular $s t r u c t u r e . 1$ FTIR spectroscopy in the torsional region with higher resolution than used $p r e v i o u s l y 1$ provided new data from which improved potential functions of both the $P F 2$ and $C H 3$ torsions were derived. The possibility of coupling of both torsions is tested using a two-dimensional $m o d e l . 2$

Description

$1$ J. R. Durig and A. W. Cox, J. Chem. Phys., 63, 2303 (1975); 64, 1930 (1976). $2$ R. Meyer, J. Mol. Spectrosc., 76, 266 (1979).

Author Institution: Department of Chemistry, University of South Carolina; Department of Chemistry, University of South Carolina

URI

http://hdl.handle.net/1811/12265

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1980-1989

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