THE STRUCTURE OF IMINOSULFUR OXYDIFLUORIDE, $HN=S(O)F_{2}$

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1977

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Ohio State University

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The microwave spectra of HNSOF2,DNSOF2,H15NSOF2 and HN34SOF2 have been measured. The molecule has a plane of symmetry containing the H, N, S, and O atoms and the hydrogen atom is trans to the oxygen atom. The following structural parameters have been determined: d(NS) = 1.466 ±0.003\AA,d(SF)=1.549±0.002\AAd(NH)=1.023±0.007\AA,<NSO=119.5±0.2∘,<NSF=112,9±0.1∘,<FSF=93.7∘±0.1∘and<HNS=115.5±0.5∘.

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Author Institution: Laboratoire de Chimie de Coordination; Department of Chemistry, The University of Michigan; Department of Chemistry, Michigan State University

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http://hdl.handle.net/1811/10131

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979