THE STRUCTURE OF IMINOSULFUR OXYDIFLUORIDE, $HN=S(O)F_{2}$
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Date
1977
Journal Title
Journal ISSN
Volume Title
Publisher
Ohio State University
Abstract
The microwave spectra of $HNSOF_{2}, DNSOF_{2}, H^{15}NSOF_{2}$ and $HN^{34}SOF_{2}$ have been measured. The molecule has a plane of symmetry containing the H, N, S, and O atoms and the hydrogen atom is trans to the oxygen atom. The following structural parameters have been determined: d(NS) = 1.466 $\pm 0.003 \AA , d(SF) = 1.549 \pm 0.002{\AA} d(NH) = 1.023 \pm 0.007{\AA} , < NSO = 119.5 \pm 0.2^\circ, < NSF = 112, 9 \pm 0.1^\circ, < FSF = 93.7^\circ \pm 0.1^\circ and < HNS = 115.5 \pm 0.5^\circ$.
Description
Author Institution: Laboratoire de Chimie de Coordination; Department of Chemistry, The University of Michigan; Department of Chemistry, Michigan State University