Knowledge Bank

We present the first interstellar detection of carbodiimide (HNCNH) in observations towards Sgr B2(N) using data from the publicly available Green Bank Telescope \textbf{PR}ebiotic \textbf{I}nterstellar \textbf{MO}lecular \textbf{S}urvey project. Recent laboratory work predicts an abundance of HNCNH of $\sim$10\%oftheabundanceofitstautomer,cyanamide(NH$_2$CN), or $\sim 2\times 1013$ cm$\mathrm{<mrow\; data-mjx-texclass="ORD">-2</mrow>}$ in Sgr B2(N). Given this abundance at LTE conditions, the strongest rotational transitions of HNCNH have intensities at or below the noise level of current observations of this source. A thermal population of HNCNH is therefore likely undetectable. Instead, HNCNH is identified via maser emission features at centimeter wavelengths. This detection presents a new methodology for the detection of low-abundance species and further demonstrates the power of cm-wave observations to make definitive identifications based on a small number of observed features.