RESONANCE RAMAN SCATTERING FROM $O3$- IONS IN Y-IRRADIATED ALKALI METAL CHLORATES AND BROMATES

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1974

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Ohio State University

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Resonance Raman scattering has been observed from O3− (ozonide) ions produced in single crystals of alkali-metal chlorates and bromates by the action of ionizing radiation. The splittings observed for the ν1 fundamental and its overtones, nν1, are attributed to multi-site effects, and the number of split components of each mode is determined by the number of non-equivalent sites occupied by O3− ions. The magnitude of the splitting observed between pairs of two-site components is proportional to the vibrational quantum number, n. Polarization measurements were used to determine the orientations of the O3− ions in the materials studied.

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This research was sponsored by the U. S. Atomic Energy Commission under contract with Union Carbide Corporation.


Author Institution: Solid State Division, Oak Ridge National Laboratory

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http://hdl.handle.net/1811/16502

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Abstracts of OSU International Symposium on Molecular Spectroscopy 1970-1979