RESONANCE RAMAN SCATTERING FROM $O3$- IONS IN Y-IRRADIATED ALKALI METAL CHLORATES AND BROMATES
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Date
1974
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Ohio State University
Abstract
Resonance Raman scattering has been observed from $O_{3}^{-}$ (ozonide) ions produced in single crystals of alkali-metal chlorates and bromates by the action of ionizing radiation. The splittings observed for the $\nu_{1}$ fundamental and its overtones, $n\nu_{1}$, are attributed to multi-site effects, and the number of split components of each mode is determined by the number of non-equivalent sites occupied by $O_{3}^{-}$ ions. The magnitude of the splitting observed between pairs of two-site components is proportional to the vibrational quantum number, n. Polarization measurements were used to determine the orientations of the $O_{3}^{-}$ ions in the materials studied.
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This research was sponsored by the U. S. Atomic Energy Commission under contract with Union Carbide Corporation.
Author Institution: Solid State Division, Oak Ridge National Laboratory
Author Institution: Solid State Division, Oak Ridge National Laboratory